Here is the complete User Manual for Niryo One, that you can download as a PDF.

This User Manual covers:

• Safety precautions when using Niryo One
• Get started with the robot
  • Use Niryo One Studio
  • Power ON and OFF the robot
  • LED color meaning
  • Use the top button
  • Connect to the robot with Wi-Fi
  • Calibrate the robot
• Command the robot
  • Learning mode
  • Move command
  • Tools
  • Digital I/Os panel
  • Saved positions
  • Niryo Blocks
  • Sequences
• Robot settings
  • Raspberry Pi 3B settings
  • Software versions
  • Hardware status
  • Debug motors